MIM at the time of skim, water soluble
adhesive additives such as polyethylene glycol or polyvinyl alcohol, can be
dissolved in warm water for easy removal. Although they are very attractive,
because of low cost, environmental impact is minimal, but can not be used in
MIM.
There are two main reasons:
A. water soluble adhesive agent is easy to
absorb moisture from the air, from solid to rubbery, dimensional stability;
B. steel powder is easy to rust.
2 why POM can be used as a binder?
A. from the chemical structure analysis:
backbone for carbon and oxygen atoms alternating structure with a certain
polarity, full contact and the surface of the metal powder; side chain hydrogen
atom and steric hindrance, the regularity of the main chain strong, so POM
crystallization degree high, generally in more than 70%, low viscosity and have
ability to maintain the shape of the green. The two characteristics estimation
can only use crystal to reconcile.
From the analysis of B. molecular weight:
POM polymerization degree is not high, easily thermal depolymerization. POM
molecular weight is small, low viscosity, ensure as far as possible the few
binder can meet the injection molding conditions. In addition, smaller
molecular weight to easily from green removal and is not easy to generate
residual stress; high degree of crystallinity, POM has good self lubrication.
C. finally, POM is a thermoplastic material
that can be recycled to reduce the cost from another aspect.
没有评论:
发表评论